Photoactivated N‐Acyliminoiodinanes Applied to Amination: an ortho‐Methoxymethyl Group Stabilizes Reactive Precursors. (13th December 2017)
- Record Type:
- Journal Article
- Title:
- Photoactivated N‐Acyliminoiodinanes Applied to Amination: an ortho‐Methoxymethyl Group Stabilizes Reactive Precursors. (13th December 2017)
- Main Title:
- Photoactivated N‐Acyliminoiodinanes Applied to Amination: an ortho‐Methoxymethyl Group Stabilizes Reactive Precursors
- Authors:
- Kobayashi, Yusuke
Masakado, Sota
Takemoto, Yoshiji - Abstract:
- Abstract: N ‐Acyliminoiodinanes were characterized for the first time by X‐ray structural analysis. The ortho ‐methoxymethyl group and the carbonyl oxygen coordinate to the iodine atom of the iminoiodinane. Activation of the N ‐acyliminoiodinane was achieved by photoirradiation at 370 nm, thereby enabling reaction with various silyl enol ethers to give α‐aminoketone derivatives in good to high yield. N ‐sulfonyliminoiodinanes bearing ortho substituents were used in photoinduced amination.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 3(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 3(2018)
- Issue Display:
- Volume 130, Issue 3 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 3
- Issue Sort Value:
- 2018-0130-0003-0000
- Page Start:
- 701
- Page End:
- 705
- Publication Date:
- 2017-12-13
- Subjects:
- α-Aminoketone -- Aminierungen -- Hypervalentes Iod -- Iminoindane -- Photoreaktionen
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201710277 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 11607.xml