Chemical characterisation of glass waste and crucible fragments from the late 17th - early 18th century Scottish glass manufacturing site at Morison's Haven, East Lothian. (April 2018)

• Record Type: Journal Article
• Authors: Spencer, Helen M.; Buckman, Jim; Forster, Alan M.; Kennedy, Craig J.
• Is Part Of: Journal of archaeological science. Volume 18(2018)
• Page Start: 437
• Page End: 446
• Publication Date: 2018-04
• Subjects: Glass waste -- Post-medieval -- Scotland -- Furnace -- Mixed alkali; Archaeology -- Periodicals; Archaeology -- Research -- Periodicals; 930.1
• DOI: 10.1016/j.jasrep.2018.01.026
• Languages: English
• ISSNs: 2352-409X

Abstract

Abstract: Glass waste and crucible fragments from the late 17th – early 18th century Scottish glass furnace at Morison's Haven, East Lothian was characterized using a range of analytical techniques (SEM-EDX, p-XRF, LA-ICP-MS and micro-XRF). Morison's Haven is the earliest excavated glass furnace in Scotland. The glass working waste provides a unique opportunity to compare the actual composition of some of the glass produced with the documentary records of raw materials used at the site and the types of glass artefacts produced. The work provides new technological and economical insights into the nature of glass production in the early 18th century in Scotland. Fourteen samples of glass working waste and three crucible fragments were examined. Two types of mixed alkali glass were found to be produced at the site neither being of a HLLA type as suggested by initial visual analysis. The first was a high quality soda-rich glass made with barilla and a pure sand source. The second type of glass was a range of lower quality mixed alkali glass at least partially fluxed with kelp ashes and using a range and mixture of less pure sand sources. This was most likely used to make windows or lower quality vessels. LA-ICP-MS analysis suggests that sand from two different sources were selected to make the two types of glass. This work is the first attempt to chemically characterize glass waste from a Scottish glass manufacturing site and adds to the known documentary and archaeological evidence to provide more knowledge pertaining to the early glass manufacturing industry in Scotland. Highlights: Glass working waste was chemically characterized from the earliest Scottish glass manufacturing furnace at Morison's Haven, East Lothian Two types of glass were identified however a continuum of compositions suggests some mixing and recycling of raw materials. The first was a high quality soda-rich glass made with barilla and a pure sand source. The second type was a lower quality mixed alkali glass partially fluxed with kelp ashes LA-ICP-MS analysis confirms that different sand and ash sources were used to make the two different types of glass