Effects of rare-earth doping on the ionic conduction of CeO2 in solid oxide fuel cells. Issue 4 (March 2018)

• Record Type: Journal Article
• Authors: Sun, Qian; Fu, Zhaoming; Yang, Zongxian
• Is Part Of: Ceramics international. Volume 44:Issue 4(2018)
• Page Start: 3707
• Page End: 3711
• Publication Date: 2018-03
• Subjects: CCV charge-compensating vacancy -- Evac formation energy -- IV intrinsic O-vacancy -- RDC rare-earth-doped ceria; Fuel cells -- Electrolyte -- Oxygen vacancy -- Ionic conductivity; Ceramics -- Periodicals; Céramique industrielle -- Périodiques; Ceramics; Periodicals; Electronic journals; 666
• DOI: 10.1016/j.ceramint.2017.11.149
• Languages: English
• ISSNs: 0272-8842

Abstract

Abstract: Rare-earth-doped CeO2 have been found to enhance the ionic conductivity of ceria-based electrolytes in solid oxide fuel cells (SOFCs) because trivalent rare-earth cations can spontaneously induce oxygen vacancies. Experimentally, it has been shown that the rare-earth elements La, Nd, Sm, Gd, Tb, Dy, and Er are likely candidates for electrolyte doping. However, the performances differ for the trivalent cations, suggesting that rare-earth doping plays multiple roles instead of only increasing the oxygen vacancies. First-principles calculations are performed on a series of rare-earth-doped CeO2 systems to study the doping effects on the ionic conductivity. It is found that the migration barriers of the oxygen ions are significantly different for the different dopants and depend on the dopant's radius. Gd-, Dy-, Er-, and Tb-doping results in small migration barriers and enhances the ionic conductivity. We also calculate the formation energies ( E vac ) of the intrinsic oxygen vacancies due to thermal excitation. It is found that the Sm- and Gd-doped ceria systems have the smallest E vac values. The electronic structures indicate that the band gaps are not sensitive to the dopant elements but are very sensitive to the fluctuations in the oxygen content.