Direct Methylation of Benzene with Methane Catalyzed by Co/MFI Zeolite. Issue 17 (11th July 2018)

• Record Type: Journal Article
• Authors: Nakamura, Koshiro; Okuda, Akihito; Ohta, Kiyotaka; Matsubara, Hitoshi; Okumura, Kazu; Yamamoto, Kana; Itagaki, Ryosuke; Suganuma, Satoshi; Tsuji, Etsushi; Katada, Naonobu
• Is Part Of: ChemCatChem. Volume 10:Issue 17(2018)
• Page Start: 3806
• Page End: 3812
• Publication Date: 2018-07-11
• Subjects: Methane -- Methylation -- Cobalt -- MFI Zeolite -- Benzene; Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201800724
• Languages: English
• ISSNs: 1867-3880

Abstract

Abstract: Cobalt‐loaded MFI zeolite showed distinct activity for direct methylation of benzene with methane into toluene. High activity was found at around 0.6 of Co/Al molar ratio. Incorporation of carbon from methane into the methyl group of toluene was confirmed with isotope tracer experiments and mass spectroscopy. Ammonia infrared‐mass spectroscopy temperature‐programmed desorption, transmission electron microscopy, X‐ray absorption near edge spectroscopy and extended X‐ray absorption fine structure indicated that Lewis acidic divalent (+II of oxidation state) Co species mono‐atomically dispersed on the ion exchange site of MFI zeolite was the active species. Abstract : Efficient methane conversion : For the direct methylation of benzene with methane, Co/MFI zeolite showed distinct catalytic activity compared to various elements/zeolites. The active species was identified to be Lewis acidic Co (oxidation state +II) species mono‐atomically dispersed on the ion exchange site of MFI zeolite.