Effect of Water, Oxygen, and Air Exposure on CH3NH3PbI3–xClx Perovskite Surface Electronic Properties. (12th September 2018)

• Record Type: Journal Article
• Authors: Ralaiarisoa, Maryline; Salzmann, Ingo; Zu, Feng‐Shuo; Koch, Norbert
• Is Part Of: Advanced Electronic Materials. Volume 4:Number 12(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-09-12
• Subjects: electronic properties -- perovskite -- photoelectron spectroscopy -- surfaces; Materials -- Electric properties -- Periodicals; Materials science -- Periodicals; Magnetic materials -- Periodicals; Electronic apparatus and appliances -- Periodicals; 537
• DOI: 10.1002/aelm.201800307
• Languages: English
• ISSNs: 2199-160X

Abstract

Abstract: The stability of hybrid perovskite materials for solar cells and high surface property reproducibility are important topics of present research. To understand the impact of water, oxygen, and air exposure, as experienced during typical device fabrication and operation conditions, on the surface electronic properties of solution‐processed CH3 NH3 PbI3– x Cl x perovskite thin films, and subsequently formed interfaces to other materials, a comprehensive photoelectron spectroscopy study is performed. It is shown that pure oxygen exposure reduces the typically observed pronounced n‐type surface character, while pure water exposure increases it. Very low water partial pressure, e.g., as encountered in inert‐gas glove boxes and in high vacuum of 10 −6 mbar, reduces the perovskite work function due to water physisorption, which is fully reversible upon mild annealing (room temperature to 50 °C) in ultrahigh vacuum. Upon exposure to ambient air, the effect of oxygen prevails over that of water, and the perovskite become less n‐type as seen by a 0.6 eV Fermi level shift toward midgap. The results help in understanding variations of the surface electronic properties reported for perovskites, which in turn impact the energy level alignment at heterojunctions in devices. For future studies, the crucial importance of stringent environment control is stressed upon. Abstract : The electronic structure of CH3 NH3 PbI3– x Cl x perovskite film surfaces is contrastingly affected by separate exposure to water and to oxygen. When acting simultaneously in air, the effect of oxygen prevails over that of water. Moreover, residual water in high vacuum and inert gas box conditions already happens to decrease the work function of perovskite films in a reversible manner.