Synthesis, Photophysical, Electrochemical Properties, DFT Studies and DSSC Performance of BODIPY Cored Triazole Bridged 3, 6‐Ditertiary Butyl Carbazole Decorated Dendrimers. Issue 32 (24th August 2018)

• Record Type: Journal Article
• Authors: Babu, Janakiraman; Ganesan, Shanmugam; Karuppusamy, Masiyappan; Rajakumar, Perumal
• Is Part Of: ChemistrySelect. Volume 3:Issue 32(2018)
• Page Start: 9222
• Page End: 9231
• Publication Date: 2018-08-24
• Subjects: BODIPY dendrimer -- Cyclic voltammetry -- 3, 6-Diteritary butyl carbazole -- DSSC; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.201801794
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: A series of BODIPY cored dendrimers up to second generation decorated with 3, 6‐ditertiary butyl carbazole at the surface and triazole as the bridging unit has been achieved by convergent approach. The synthesised dendrimers show excellent photophysical and electrochemical properties. All the dendrimers exhibit bi‐exponential lifetime decay, with the higher generation dendrimers (G2 ) exhibiting longer lifetime decay than the lower generation dendrimers. Density functional theory calculations on the synthesized dendrimers show the HOMO – LUMO energy gap as 2.42 eV with predicted absorption maximum around 425 nm. Cyclic voltammetric studies reveal that all the dendrimers exhibit irreversible oxidation‐reduction signal. Higher generation dendrimer (G2 ) shows a better power conversion efficiency of 2.7% than the other synthesised dendrimers when used as sensitizer in DSSC. Abstract : BODIPY cored 3, 6‐diteritary butyl carbazole dendrimers were synthesised successfully using click chemistry. All the dendrimer exhibits excellent photophysical and electrochemical properties and also supported by DFT calculations. When used as dye/sensitizer in DSSC, the higher generation dendrimer (second generation) shows a higher efficiency of 2.7%.