Palladium‐Catalyzed Ligand‐Free Suzuki–Miyaura Reaction of Aryl Fluorosulfates and Various Arylboron Compounds. Issue 43 (21st November 2018)

• Record Type: Journal Article
• Authors: Li, Xinmin; Zhang, Hang; Feng, Fangfang; Hu, Qinghong; Yuan, Zeli
• Is Part Of: ChemistrySelect. Volume 3:Issue 43(2018)
• Page Start: 12287
• Page End: 12290
• Publication Date: 2018-11-21
• Subjects: Arylboron Compounds -- Aryl Fluorosulfate -- Ligand-free -- One-pot -- Suzuki–Miyaura reaction; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.201802120
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: A practical and efficient protocol for the synthesis of biaryl products in good yields by a ligand‐free palladium catalyzed Suzuki–Miyaura reaction of aryl fluorosulfates and various arylboron compounds has been developed. Moreover, we report a one‐pot tandem method for conversion of phenol derivatives to aryl fluorosulfates, and subsequent cross‐coupling to form biaryls. Abstract : We here report a practical and efficient protocol for the ligand‐free palladium catalyzed Suzuki–Miyaura reaction of aryl fluorosulfate and various arylboron compounds, which provided corresponding product in excellent yields with good functional group compatibility. In addition, a one‐pot tandem method for conversion of phenol derivatives to aryl fluorosulfate, and subsequent cross‐coupling to form biaryls was developed.