Evidence of Phosphonium‐Carbenium Dication Formation in a Superacid: Precursor to Fluorinated Phosphine Oxides. (28th December 2018)
- Record Type:
- Journal Article
- Title:
- Evidence of Phosphonium‐Carbenium Dication Formation in a Superacid: Precursor to Fluorinated Phosphine Oxides. (28th December 2018)
- Main Title:
- Evidence of Phosphonium‐Carbenium Dication Formation in a Superacid: Precursor to Fluorinated Phosphine Oxides
- Authors:
- Castelli, Ugo
Lohier, Jean‐François
Drukenmüller, Ines
Mingot, Agnès
Bachman, Christian
Alayrac, Carole
Marrot, Jérôme
Stierstorfer, Karin
Kornath, Andreas
Gaumont, Annie‐Claude
Thibaudeau, Sébastien - Abstract:
- Abstract: Unambiguously confirmed by low‐temperature in situ NMR experiments, X‐ray diffraction and vibrational spectroscopy, phosphonium‐carbenium superelectrophiles are shown to be generated in strong acidic conditions. Representing crucial intermediates, their exploitation allows for the synthesis of unprecedented fluorinated (cyclic) phosphine oxides.
- Is Part Of:
- Angewandte Chemie. Volume 131:Number 5(2019)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 131:Number 5(2019)
- Issue Display:
- Volume 131, Issue 5 (2019)
- Year:
- 2019
- Volume:
- 131
- Issue:
- 5
- Issue Sort Value:
- 2019-0131-0005-0000
- Page Start:
- 1369
- Page End:
- 1374
- Publication Date:
- 2018-12-28
- Subjects:
- Cyclisierungen -- Fluorierungen -- Phosphanoxid -- Superelektrophile -- Supersäuren
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201811032 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 11502.xml