A new Cd(ii)-based metal–organic framework for highly sensitive fluorescence sensing of nitrobenzene. Issue 12 (27th February 2015)

• Record Type: Journal Article
• Authors: Xia, Yu-Pei; Li, Yun-Wu; Li, Da-Cheng; Yao, Qing-Xia; Du, Yu-Chang; Dou, Jian-Min
• Is Part Of: CrystEngComm. Volume 17:Issue 12(2015)
• Page Start: 2459
• Page End: 2463
• Publication Date: 2015-02-27
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c5ce00162e
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : A Cd(ii )-based MOF was synthesized from a new flexible multidentate ligand H4 L . The MOF reveals different fluorescence responses to various organic analytes. This phenomenon indicates that this MOF may be a good probe for detecting nitrobenzene. Abstract : A Cd(ii )-based metal–organic framework, {[Cd2 L(H2 O)2 ]·DMF·H2 O} n (1 ), has been successfully constructed from a new flexible antler-like multidentate ditopic ligand (H4 L ). This metal–organic framework shows highly sensitive fluorescence sensing of nitrobenzene.