Cation–anion double hydrolysis derived layered single metal hydroxide superstructures for boosted supercapacitive energy storage. Issue 27 (16th June 2015)

• Record Type: Journal Article
• Authors: Gu, C. D.; Ge, X.; Wang, X. L.; Tu, J. P.
• Is Part Of: Journal of materials chemistry. Volume 3:Issue 27(2015)
• Page Start: 14228
• Page End: 14238
• Publication Date: 2015-06-16
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c5ta03140k
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : A double hydrolysis reaction provides a simple strategy to construct layered single hydroxides with superstructures for electrochemical energy storage. Abstract : As promising battery-type electrode materials, layered single metal hydroxides (LSHs) including α-Ni(OH)2 and α-Co(OH)2 based hybrid supercapacitors exhibit larger operating voltages compared with those that are based on activated carbons and double-layer capacitance mechanisms. This study proposes a novel and facile room-temperature method to fabricate α-Ni(OH)2 and α-Co(OH)2 superstructures by using the double hydrolysis of Ni 2+ or Co 2+ and NCO − without the presence of any structure directing agent. Two dimensional sheet-like building blocks of the alpha-type metal hydroxide are assembled into various elegant morphologies including a 3D interconnected hierarchical assembly (3D-ICHA), sheet-on-sheet, sheet-on-rod and other nanostructures, which depends on the cation–anion mixing mode. Significantly, the 3D-ICHA α-Ni(OH)2 possesses an ultrahigh specific surface area (320.2 m 2 g −1 ) and robust porous structure. An outstanding initial specific capacity (653.1 C g −1 at 1 A g −1 and 406 C g −1 at 20 A g −1 ) and an excellent cycling retention (86.2% in 20 000 cycles) were obtained for the 3D-ICHA α-Ni(OH)2, which stands out from most of the state-of-the-art α-Ni(OH)2 powder-based materials. A high-loading asymmetric capacitor with excessive activated carbon (∼10 mg 3D-ICHA α-Ni(OH)2 vs. ∼60 mg activated carbon) is demonstrated and it works very steadily even after 20 000 charge/discharge cycles.