Millipede-inspired structural design principle for high performance polysaccharide binders in silicon anodes. Issue 4 (11th February 2015)

• Record Type: Journal Article
• Authors: Jeong, You Kyeong; Kwon, Tae-woo; Lee, Inhwa; Kim, Taek-Soo; Coskun, Ali; Choi, Jang Wook
• Is Part Of: Energy & environmental science. Volume 8:Issue 4(2015)
• Page Start: 1224
• Page End: 1230
• Publication Date: 2015-02-11
• Subjects: Energy conversion -- Periodicals; Fuel switching -- Periodicals; Environmental sciences -- Periodicals; Environmental chemistry -- Periodicals; 333.79
• DOI: 10.1039/c5ee00239g
• Languages: English
• ISSNs: 1754-5692

Abstract

Abstract : The millipede's extraordinary adhesion provides a design principle for silicon anode binders with emphasis on the superstructure and electrostatic charge. Abstract : We systematically investigate polysaccharide binders for high-capacity silicon anodes in lithium ion batteries to find critical factors for the binder function. Analogous to the millipede's strong adhesion based on adhesive pads located on each leg, xanthan gum exhibits the best performance by utilizing its double helical superstructure with side chains and ion–dipole interactions, revealing the great importance of the superstructure and charge interactions in the Si binder design.