Determination of the mechanical properties of SnSe, a novel layered semiconductor. (May 2018)

• Record Type: Journal Article
• Authors: Lamuta, Caterina; Campi, Davide; Pagnotta, Leonardo; Dasadia, Abhay; Cupolillo, Anna; Politano, Antonio
• Is Part Of: Journal of physics and chemistry of solids. Volume 116(2018)
• Page Start: 306
• Page End: 312
• Publication Date: 2018-05
• Subjects: Nanoindentation -- Layered materials -- Density functional theory -- Mechanical properties; Solids -- Periodicals; Solides -- Périodiques; Solids; Periodicals; 530.41
• DOI: 10.1016/j.jpcs.2018.01.045
• Languages: English
• ISSNs: 0022-3697

Abstract

Abstract: Tin selenide (SnSe) is one the most promising materials for flexible electronics. However, experiments on the direct determination of its mechanical properties are still missing. By means of depth-sensing nanoindentation experiments, we directly evaluate the Young's modulus of bulk single crystals of tin selenide (25.3 GPa), as well as their hardness (0.82 GPa). Experimental results are compared with predictions by density functional theory, performed using eleven different functionals. The discrepancies between the experimental results and the thoretical predictions can be ascribed to the oxidation of the SnSe surface, detected by X-ray photoelectron spectroscopy. Highlights: We have studied by depth-sensing nanoindentation the Young's modulus and the hardness of highly crystalline single crystals of SnSe. We show that SnSe is a superflexible layered semiconductor. SnSe has been grown by chemical vapor transport Theoretical reproduction of our results by different functionals