Applications of Diphosphines in Radical Reactions. Issue 8 (23rd July 2019)

• Record Type: Journal Article
• Authors: Kawaguchi, Shin‐ichi; Ogawa, Akiya
• Is Part Of: Asian journal of organic chemistry. Volume 8:Issue 8(2019)
• Page Start: 1164
• Page End: 1173
• Publication Date: 2019-07-23
• Subjects: phosphanes -- radical reactions -- photochemistry -- radicals; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; 547.005
• DOI: 10.1002/ajoc.201900339
• Languages: English
• ISSNs: 2193-5807

Abstract

Abstract: Recently, the importance of organophosphorus compounds in organic chemistry has increased. Diphosphines are an attractive source of phosphorus containing two phosphorus groups, which can theoretically be introduced into a carbon framework with high atom economy. There are several diphosphine derivatives, which are closely related to diphosphines, but their reactivities are completely different. In this Minireview, we describe various phosphination reactions with diphosphines and their derivatives under radical conditions. Abstract : Pew‐Pew ! Diphosphines are an attractive source of phosphorus containing two phosphorus groups. There are several diphosphine derivatives, which are closely related to diphosphines, but their reactivities are completely different. In this Minireview, various phosphination reactions with diphosphines and their derivatives under radical conditions are described.