Symmetric and non-symmetric bis-metallylene iron complexes, precursors of iron germanide nanoparticles. Issue 64 (23rd July 2019)

• Record Type: Journal Article
• Authors: Sodreau, Alexandre; Lentz, Nicolas; Frutos, Maria; Mallet-Ladeira, Sonia; Nayral, Céline; Delpech, Fabien; Madec, David
• Is Part Of: Chemical communications. Volume 55:Issue 64(2019)
• Page Start: 9539
• Page End: 9542
• Publication Date: 2019-07-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c9cc05063a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Symmetric and non-symmetric bis-metallylene iron complexes are described. A bis-germylene Fe(CO)3 complex has been applied in the synthesis of iron germanide nanocrystals. Abstract : We report herein the synthesis of symmetric and non-symmetric bis-amidinato-germylene Fe(CO)3 complexes, as well as the preparation of the corresponding disymmetric germylene–stannylene and germylene–silylene complexes by selective displacement of a carbonyl ligand under UV-a light irradiation. The symmetric bis-germylene Fe(CO)3 complex has been applied in the synthesis of iron germanide nanocrystals.