1, 2-Bis(arylthio)arene synthesis via aryne intermediates. Issue 64 (22nd July 2019)
- Record Type:
- Journal Article
- Title:
- 1, 2-Bis(arylthio)arene synthesis via aryne intermediates. Issue 64 (22nd July 2019)
- Main Title:
- 1, 2-Bis(arylthio)arene synthesis via aryne intermediates
- Authors:
- Mesgar, Milad
Nguyen-Le, Justin
Daugulis, Olafs - Abstract:
- Abstract : Use of a bulky LDAM base allows for an efficient synthesis of 1, 2-bis(arylthio)arenes from aryl halides and triflates. Abstract : Lithium 1, 1-diadamantylamide (LDAM) base-promoted insertion of arynes into disulfide S–S bonds is described. After generation of arynes from readily available aryl halides and triflates, reactions with diaryl and diisopropyl disulfides afford the insertion products in moderate to excellent yields. Use of 1-cyclohexenyl triflate gave an excellent yield of 1, 2-bis(phenylthio)cyclohexene.
- Is Part Of:
- Chemical communications. Volume 55:Issue 64(2019)
- Journal:
- Chemical communications
- Issue:
- Volume 55:Issue 64(2019)
- Issue Display:
- Volume 55, Issue 64 (2019)
- Year:
- 2019
- Volume:
- 55
- Issue:
- 64
- Issue Sort Value:
- 2019-0055-0064-0000
- Page Start:
- 9467
- Page End:
- 9470
- Publication Date:
- 2019-07-22
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9cc03863a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 11355.xml