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Enhanced catalytic activity of cobalt nanoparticles encapsulated with an N-doped porous carbon shell derived from hollow ZIF-8 for efficient synthesis of nitriles from primary alcohols in water. Issue 16 (2nd August 2019)
Record Type:
Journal Article
Title:
Enhanced catalytic activity of cobalt nanoparticles encapsulated with an N-doped porous carbon shell derived from hollow ZIF-8 for efficient synthesis of nitriles from primary alcohols in water. Issue 16 (2nd August 2019)
Main Title:
Enhanced catalytic activity of cobalt nanoparticles encapsulated with an N-doped porous carbon shell derived from hollow ZIF-8 for efficient synthesis of nitriles from primary alcohols in water
Abstract : A cobalt catalyst derived from a unique core–shell structure based on hollow ZIF-8 and ZIF-67 is prepared for the synthesis of nitriles from alcohols in water under mild conditions. Abstract : A cobalt catalyst derived from a unique core–shell structure based on hollow ZIF-8 and ZIF-67 (ZIF-67@ZIF-8) is prepared, which exhibits excellent catalytic efficiency for the synthesis of nitriles from alcohols in water under mild conditions (1 atm O2, 50 °C) owing to its large BET surface area, high pore volume, high basicity and hydrophilicity.