Synthesis of 2-substituted hydroquinone derivatives from 1, 4-benzoquinone and allyl ethers. Issue 18 (3rd May 2018)
- Record Type:
- Journal Article
- Title:
- Synthesis of 2-substituted hydroquinone derivatives from 1, 4-benzoquinone and allyl ethers. Issue 18 (3rd May 2018)
- Main Title:
- Synthesis of 2-substituted hydroquinone derivatives from 1, 4-benzoquinone and allyl ethers
- Authors:
- Kaurich, Kevin J.
Deck, Paul A. - Abstract:
- Abstract: B -Alkylpinacolboranes, derived from rhodium-catalyzed hydroboration of allyl ethers with pinacolborane, react with 1, 4-benzoquinone under acidic, oxidizing conditions, to afford, after subsequent hydrogenation, 2-substituted hydroquinones in isolated, purified yields of about 50% based on 1, 4-benzoquinone. The product hydroquinones have potential use as precursors to poly(arylene ether) and related aromatic polymers. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 74:Issue 18(2018)
- Journal:
- Tetrahedron
- Issue:
- Volume 74:Issue 18(2018)
- Issue Display:
- Volume 74, Issue 18 (2018)
- Year:
- 2018
- Volume:
- 74
- Issue:
- 18
- Issue Sort Value:
- 2018-0074-0018-0000
- Page Start:
- 2191
- Page End:
- 2196
- Publication Date:
- 2018-05-03
- Subjects:
- Hydroboration -- Hydroquinone -- Benzoquinone -- Wilkinson's catalyst
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2018.01.048 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 11346.xml