Novel preparation of an ancient ceramic pigment BaCuSi4O10 and its performance investigation. (May 2018)

• Record Type: Journal Article
• Authors: Zhang, Chaowu; Zhang, Nan; Wang, Xiayun; Zhang, Lina
• Is Part Of: Materials research bulletin. Volume 101(2018)
• Page Start: 334
• Page End: 339
• Publication Date: 2018-05
• Subjects: BaCuSi4O10 -- Chinese blue -- Coprecipitation and hydrothermal process -- Calcination; Materials -- Periodicals; Crystal growth -- Periodicals; Matériaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Crystal growth; Materials; Periodicals; 620.11
• DOI: 10.1016/j.materresbull.2018.02.002
• Languages: English
• ISSNs: 0025-5408

Abstract

Graphical abstract: Highlights: The BaCuSi4 O10 (Chinese blue) was prepared firstly by coprecipitation and hydrothermal process at 180 °C for 20 h, and then sintered at 800 °C, resulting in pigment with superior performance. The as-prepared pigment possesses bright blue coloration, preferable flower-like mesoporous microspheres morphology and qualified purity. This novel process could fabricate the BaCuSi4 O10 pigment with broadband optical absorption and better emission in the near-infrared region. This novel process decreases the calcination temperature compared with the traditional solid state method and also lowers the hydrothermal temperature and time compared with only a sole hydrothermal process. Abstract: The BaCuSi4 O10 (Chinese blue) was prepared by coprecipitation and hydrothermal process at 180 °C for 20 h prior to sintering at 800 °C with a final pigment of superior performance. The crystalline configuration and microstructure of the product were characterized by XRD, FTIR, SEM and TEM. The electronic structure and the valence situation were determined by XPS. The coloration was studied with colorimeter. The absorption and the luminescence properties were examined with an UV−VIS-NIR spectrometer and a spectrofluorimeter, respectively. The results show that the BaCuSi4 O10 pigment prepared by this combined fabrication process possesses flower-like mesoporous microspheres morphology, better crystallization, clear coloration and rather qualified purity. The as-prepared BaCuSi4 O10 pigment also shows well optical property with broadband absorption and better emission in the 800–1200 nm range. Compared with traditional solid state fabrication or only sole hydrothermal process, this novel process can also reduce hydrothermal temperature and time, and decrease calcination temperature.