BiI3 mediated difunctionalization of α-methylstyrenes, including azidohydroxylation and azidoiodination. Issue 9 (1st March 2018)
- Record Type:
- Journal Article
- Title:
- BiI3 mediated difunctionalization of α-methylstyrenes, including azidohydroxylation and azidoiodination. Issue 9 (1st March 2018)
- Main Title:
- BiI3 mediated difunctionalization of α-methylstyrenes, including azidohydroxylation and azidoiodination
- Authors:
- Hsueh, Nai-Chen
Chan, Chieh-Kai
Chang, Meng-Yang - Abstract:
- Abstract: BiI3 mediated vicinal azidohydroxylation of α-methylstyrenes1 with NaN3 in wet DMF affords β-azidoalcohols4 in good yields. In dry DMF, β-azidoiodides6 are also obtained by BiI3 mediated vicinal azidoiodination of α-methylstyrenes1 with NaN3 . This present protocol provides the bond formations of carbon-azido/carbon-hydroxy ( N 3 ─CC─ OH ) bond and carbon-azido/carbon-iodo ( N 3 ─CC─ I ) under water-controlled conditions. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 74:Issue 9(2018)
- Journal:
- Tetrahedron
- Issue:
- Volume 74:Issue 9(2018)
- Issue Display:
- Volume 74, Issue 9 (2018)
- Year:
- 2018
- Volume:
- 74
- Issue:
- 9
- Issue Sort Value:
- 2018-0074-0009-0000
- Page Start:
- 1002
- Page End:
- 1008
- Publication Date:
- 2018-03-01
- Subjects:
- Bismuth iodide -- Azidohydroxylation -- α-methylstyrenes -- β-Azidoalcohols
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2018.01.023 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 11319.xml