Post‐synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex. Issue 14 (26th June 2018) - Komatsumaru, Yuki
Abstract : The dinuclear iron(III) complex [Fe(salten)2 (bipytz)](BPh4 )2 · EtOH (1 ) was synthesized and its post‐synthesis modification yielded [Fe(salten)2 (bipydz)](BPh4 )2 · EtOH (2 ). The crystal structures and magnetic behaviors of1 and2 were investigated by variable temperature XRD, magnetic susceptibility, and Mössbauer spectra measurements, with each of these dinuclear iron(III) complexes exhibiting gradual spin crossover behavior. Abstract :