Organic Mesopore Generating Agents (OMeGAs) for Hierarchical Zeolites: Combining Functions on Multiple Scales. Issue 7 (11th June 2019) - Hong, Mei
Abstract: In the synthesis of porous zeolites, small organic molecules usually function as organic structure‐directing agents (OSDAs) or zeolite growth modifiers (ZGMs), while mesoporous zeolites are typically synthesized by employing the physical space‐filling strategy with mesoscale templates including carbons, surfactants, and polymers. Recently, we discovered that a class of small organic molecules including the common amino acids could mediate the formation of zeolite mesopores based on a chemical bond‐breaking mechanism. This class of organic mesopore generating agents (OMeGAs) are distinguished by their ability to form organic anions in situ. In this minireview, we briefly introduce the widely recognized role of OSDA and ZGM, and then focus on the interesting function of OMeGA for the intracrystalline void generation. Comparison of OMeGA with the mesoscale templates especially surfactants are made in terms of their mesopore‐forming mechanisms, and the potential implications on a possible dissociative‐associative crystallization pathway are discussed. We end this review with the prospects of future research on the small molecule OMeGA, such as function integration and structure optimization. Abstract : Controlled porosity : Organic mesopore generating agents (OMeGAs) combine the features of conventional organic small molecules and organic mesoporogens in zeolite engineering. This minireview gives an overview of this topic and discusses future prospects.