Physical Synthesis and Study of Ag@CaF2 Core@Shell Nanoparticles: Morphology and Tuning of Optical Properties. Issue 7 (20th February 2019)

• Record Type: Journal Article
• Authors: D'Addato, Sergio; Vikatakavi, Avinash; Spadaro, Maria Chiara; Valeri, Sergio; Pasquali, Luca
• Is Part Of: Physica status solidi. Volume 256:Issue 7(2019)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-02-20
• Subjects: Ag nanoparticles -- core–shell nanoparticles -- optical reflectvity -- surface plasmon resonance -- scanning electron microscopy -- X‐ray photoelectron spectroscopy; Solid state physics -- Periodicals; Solids -- Periodicals; Atomic structure -- Periodicals; 530.41
• DOI: 10.1002/pssb.201800507
• Languages: English
• ISSNs: 0370-1972

Abstract

Abstract : Pre‐formed Ag nanoparticles (NPs) and Ag@CaF2 core–shell NPs are physically synthesized using DC magnetron‐based NP source and deposited on Si‐SiOx wafers. The samples are prepared by co‐depositing Ag nanoparticles and CaF2 produced by an evaporation source, or by sequential deposition method, i.e., by depositing in a sequence a CaF2 buffer layer, the Ag NPs generated by the NP source and a capping CaF2 layer. The supported films are characterized by Scanning Electron Microscopy (SEM), X‐ray Photoelectron Spectroscopy (XPS), and Surface Differential Reflectivity (SDR). SEM shows that Ag NPs deposited directly on Si‐SiOx tend to diffuse and to agglomerate, affecting the size distribution of the nanostructures. The presence of a CaF2 buffer layer between Ag and Si‐SiOx limits this effect, while XPS reveals electrical charging, caused by the insulating nature of the CaF2 continuous film. The surface plasmon resonance behavior for different samples is analyzed using SDR with p‐polarized light. There is a clear evidence of a blue shift in the plasmon excitation due to the presence of CaF2 on Si, which can represent a potential advantage for the technological applications in photovoltaics and optoelectronics. Abstract : Ag nanoparticles (NPs) and Ag@CaF2 core–shell NP films are prepared either by co‐depositing Ag nanoparticles and CaF2, or as a CaF2 /Ag NP/CaF2 trilayer. While Ag NPs deposited on Si‐SiOx diffuse and agglomerate, the presence of a CaF2 buffer layer between Ag and Si‐SiOx substrate limits this effect. p‐polarized optical measurements reveal blue shift in the plasmon excitation due to the presence of CaF2 on Si.