Nanofluid Based on Glucose‐Derived Carbon Dots Functionalized with [Bmim]Cl for the Next Generation of Smart Windows. (7th June 2019)

• Record Type: Journal Article
• Authors: Gonçalves, Helena M. R.; Pereira, Rui F. P.; Lepleux, Emmanuel; Carlier, Thomas; Pacheco, Louis; Pereira, Sónia; Valente, Artur J. M.; Fortunato, Elvira; Duarte, Abel J.; de Zea Bermudez, Verónica
• Is Part Of: Advanced sustainable systems. Volume 3:Number 7(2019)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-06-07
• Subjects: carbon dots -- integrated thermotropic–electrochromic devices -- ionic liquids -- self‐regenerating -- smart windows; Sustainable living -- Periodicals; Sustainability -- Periodicals; Green technology -- Periodicals; Periodicals; 628
• DOI: 10.1002/adsu.201900047
• Languages: English
• ISSNs: 2366-7486

Abstract

Abstract: The design of new advanced materials and technologies is essential for the development of smart windows for the next generation of energy‐efficient buildings. Here, it is demonstrated that the functionalization of glucose‐derived carbon dots with 1‐butyl‐3‐methylimidazolium chloride results in a self‐standing, water‐soluble, viscous, reusable nanofluid with self‐improving conductivity, thermotropy around 30–40 °C, and ultraviolet blocking ability. Its synthesis is straightforward, clean, fast, and cheap. At 36 °C (hot summer day), a sun‐actuated thermotropic (TT) device incorporating a 95% w/w nanofluid aqueous solution exhibits a transmittance variation (Δ T ) of 9% at 550/1000 nm, which is amplified to 47/31% via the surface plasmon resonance effect. An integrated self‐healing system enabling independent sun‐actuated TT and voltage‐actuated electrochromic (EC) operation is also produced. The low‐energy EC device offers bright hot and dark cold modes (Δ T = 68/64%), excellent cycling stability, unprecedented coloration efficiency values (−1.73 × 10 6 /−1.67 × 10 6 cm 2 C −1 (coloring) and +1.12 × 10 7 /+1.08 × 10 7 cm 2 C −1 (bleaching) at ±2.5 V), and impressive memory effect. The disruptive design and sustainable synthesis of the new nanofluid proposed here will foster the agile development of novel products with improved ecological footprint. Abstract : A new nanofluid composed of glucose‐derived carbon dots functionalized with an ionic liquid demonstrates tremendous potential for smart windows technology. Its synthesis is straightforward, green and cost‐effective. It exhibits thermotropy at 30–40 ºC, self‐healing, non‐Newtonian behavior, and ultraviolet blocking ability. It enables the production of a thermotropic device with plasmonic‐enhanced performance, and an independently operated thermotropic/electrochromic integrated device with unprecedented features.