A new proton-conducting Bi-carboxylate framework. Issue 30 (2nd July 2019)

• Record Type: Journal Article
• Authors: Vilela, Sérgio M. F.; Devic, Thomas; Várez, Alejandro; Salles, Fabrice; Horcajada, Patricia
• Is Part Of: Dalton transactions. Volume 48:Issue 30(2019)
• Page Start: 11181
• Page End: 11185
• Publication Date: 2019-07-02
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9dt02009h
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A new robust Bi-carboxylate metal–organic framework (MOF) IEF-2 was hydrothermally prepared, acting as a proton carrier ( σ ∼ 1.1 × 10 −4 S cm −1 ). Abstract : A new robust Bi-carboxylate metal–organic framework (MOF) IEF-2 was hydrothermally prepared, acting as a proton carrier ( σ ∼ 1.1 × 10 −4 S cm −1 ). Such proton conductivity is among the highest reported so far for purely 3D carboxylate-based MOFs, being explained by the existence of a 1D hydrogen-bond network, as suggested by structural analysis and theoretical studies.