X-ray diffraction analysis for the determination of elastic properties of zinc-doped manganese spinel ferrite nanocrystals (Mn0.75Zn0.25Fe2O4), along with the determination of ionic radii, bond lengths, and hopping lengths. (November 2019)

• Record Type: Journal Article
• Authors: Debnath, Simi; Deb, Krishna; Saha, Biswajit; Das, Ratan
• Is Part Of: Journal of physics and chemistry of solids. Volume 134(2019)
• Page Start: 105
• Page End: 114
• Publication Date: 2019-11
• Subjects: Spinel ferrite nanocrystals -- X-ray diffraction -- Elastic properties -- Williamson-Hall plot -- Size-strain plot; Solids -- Periodicals; Solides -- Périodiques; Solids; Periodicals; 530.41
• DOI: 10.1016/j.jpcs.2019.05.047
• Languages: English
• ISSNs: 0022-3697

Abstract

Abstract: Zinc-doped manganese spinel ferrite nanocrystals with chemical formula Mn0.75 Zn0.25 Fe2 O4 were synthesized by the chemical co-precipitation method. The structural properties of the synthesized nanoparticles were studied by X-ray diffraction analysis (XRD), whereas morphological analysis was performed by high-resolution transmission electron microscopy (HR-TEM) and scanning electron microscopy. The XRD study confirmed the formation of single-phase spinel face-centered cubic nanocrystals with an average size of approximately 19 nm. HR-TEM analysis gave an average particle size of approximately 15 nm, with the nanocrystals being almost spherical. The selected-area electron diffraction pattern obtained in the HR-TEM study clearly indicated the polycrystalline nature of the nanocrystals. The Fourier transform infrared spectrum confirmed the formation of a pure spinel ferrite structure. Williamson-Hall plot analysis, using the XRD data, was used to obtain information on the different elastic properties, such as residual strain, stress, and energy density, considering the uniform deformation model, the uniform stress deformation model, and the uniform deformation energy density model. The results were compared with the results obtained by the size-strain plot method. The XRD data were used to determine the lattice parameter, which was found to be 0.81 nm. With use of the calculated lattice parameter, the ionic radii, bond lengths of the tetrahedral and octahedral sites, and hopping lengths of the spinel ferrite nanocrystals were calculated. Finally, a magnetic study using a vibrating-sample magnetometer showed that the nanocrystal sample is superparamagnetic. Graphical abstract: Size-strain plot for the determination of the size and strain value for the prepared zinc doped manganese spinel ferrite using the XRD data.Image 1 Highlights: Mn0.75 Zn0.25 Fe2 O4 nanoparticles were prepared by the co-precipitation method. The high-resolution transmission electron microscopy images show that the average size is approximately 15 nm. Different elastic parameters were studied by a Williamson-Hall plot using X-ray diffraction analysis. The ionic radii, bond lengths, and hoping lengths were calculated. .