Enantioselective Intramolecular Copper‐Catalyzed Borylacylation. (21st September 2018)
- Record Type:
- Journal Article
- Title:
- Enantioselective Intramolecular Copper‐Catalyzed Borylacylation. (21st September 2018)
- Main Title:
- Enantioselective Intramolecular Copper‐Catalyzed Borylacylation
- Authors:
- Whyte, Andrew
Burton, Katherine I.
Zhang, Jingli
Lautens, Mark - Abstract:
- Abstract: An enantioselective copper‐catalyzed intramolecular borylacylation is reported. The reaction proceeds through an initial enantioselective borylcupration of the styrene, followed by a nucleophilic attack on the tethered carbamoyl chloride. The products, chiral borylated 3, 3‐disubstituted oxindoles, were generated in excellent yields and enantioselectivities. The versatile carbon–boron bond provides a platform for a wide array of diversification.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 42(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 42(2018)
- Issue Display:
- Volume 130, Issue 42 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 42
- Issue Sort Value:
- 2018-0130-0042-0000
- Page Start:
- 14123
- Page End:
- 14126
- Publication Date:
- 2018-09-21
- Subjects:
- Asymmetrische Katalyse -- Bor -- Cyclisierungen -- Heterocyclen -- Kupfer
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201808460 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 11230.xml