Transformation of Organostannanes Based on Photocleavage of C-Sn Bond via Single Electron Transfer Process. Issue 1 (December 2017)

• Record Type: Journal Article
• Authors: Li, Han; Jin, Ruiwen; Li, Yawei; Ding, Aishun; Hao, Xinqi; Guo, Hao
• Is Part Of: Scientific reports. Volume 7:Issue 1(2017)
• Page Start: 1
• Page End: 7
• Publication Date: 2017-12
• Subjects: Natural history -- Research -- Periodicals; Biology -- Research -- Periodicals; Physical sciences -- Research -- Periodicals; Earth sciences -- Research -- Periodicals; Environmental sciences -- Research -- Periodicals; 502.85
• DOI: 10.1038/s41598-017-16806-3
• Languages: English
• ISSNs: 2045-2322

Abstract

Abstract In this work, we developed a new method for the transformation of organostannanes via radical process. In this reaction, highly reactive carbon radical species can be efficiently generated through HBr-catalyzed photocleavage of C-Sn bond via single electron transfer process. Under aerobic conditions, thein situ formed primary/secondary alkyl radicals can be further highly selectively oxidized into carboxylic acids/ketones, respectively.