Base-catalysed reductive relay hydroboration of allylic alcohols with pinacolborane to form alkylboronic esters. Issue 60 (7th June 2019)
- Record Type:
- Journal Article
- Title:
- Base-catalysed reductive relay hydroboration of allylic alcohols with pinacolborane to form alkylboronic esters. Issue 60 (7th June 2019)
- Main Title:
- Base-catalysed reductive relay hydroboration of allylic alcohols with pinacolborane to form alkylboronic esters
- Authors:
- Wang, Zi-Chao
Shen, Di
Gao, Jian
Jia, Xian
Xu, Youjun
Shi, Shi-Liang - Abstract:
- Abstract : A novel reductive relay hydroboration of allylic alcohols with pinacolborane using n BuLi as an efficient initiator is reported. Abstract : An unprecedented base-catalysed reductive relay hydroboration of allylic alcohols is described. Commercially available n BuLi was found to be a robust transition metal-free initiator for this protocol, affording various boronic esters in high yield and selectivity. Mechanistically, this methodology involves a one-pot three-step successive process (dehydrocoupling/allylic hydride substitution/anti-Markovnikov hydroboration).
- Is Part Of:
- Chemical communications. Volume 55:Issue 60(2019)
- Journal:
- Chemical communications
- Issue:
- Volume 55:Issue 60(2019)
- Issue Display:
- Volume 55, Issue 60 (2019)
- Year:
- 2019
- Volume:
- 55
- Issue:
- 60
- Issue Sort Value:
- 2019-0055-0060-0000
- Page Start:
- 8848
- Page End:
- 8851
- Publication Date:
- 2019-06-07
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9cc03459e ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 11174.xml