Phosphonic acid mediated practical dehalogenation and benzylation with benzyl halides. Issue 39 (18th July 2019)
- Record Type:
- Journal Article
- Title:
- Phosphonic acid mediated practical dehalogenation and benzylation with benzyl halides. Issue 39 (18th July 2019)
- Main Title:
- Phosphonic acid mediated practical dehalogenation and benzylation with benzyl halides
- Authors:
- Xiao, Jing
Ma, Yonghao
Wu, Xiaofang
Gao, Jing
Tang, Zilong
Han, Li-Biao - Abstract:
- Abstract : A practical method for phosphonic acid mediated dehalogenation and benzylation with benzyl halides was developed. Abstract : For the first time, by using H3 PO3 /I2 system, various benzyl chlorides, bromides and iodides were dehalogenated successfully. In the presence of H3 PO3, benzyl halides underwent electrophilic substitution reactions with electron-rich arenes, leading to a broad range of diarylmethanes in good yields. These transformations feature green, cheap reducing reagents and metal-free conditions. A possible mechanism was proposed.
- Is Part Of:
- RSC advances. Volume 9:Issue 39(2019)
- Journal:
- RSC advances
- Issue:
- Volume 9:Issue 39(2019)
- Issue Display:
- Volume 9, Issue 39 (2019)
- Year:
- 2019
- Volume:
- 9
- Issue:
- 39
- Issue Sort Value:
- 2019-0009-0039-0000
- Page Start:
- 22343
- Page End:
- 22347
- Publication Date:
- 2019-07-18
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/RA ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9ra04770k ↗
- Languages:
- English
- ISSNs:
- 2046-2069
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8036.750300
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 11153.xml