Modulating lifetimes and relaxation times of phenoxyl radicals through their incorporation into different hybrid nanostructures. Issue 29 (16th July 2019)

• Record Type: Journal Article
• Authors: Dol, Cyrielle; Gerbaud, Guillaume; Guigliarelli, Bruno; Bloch, Emily; Gastaldi, Stéphane; Besson, Eric
• Is Part Of: Physical chemistry chemical physics. Volume 21:Issue 29(2019)
• Page Start: 16337
• Page End: 16344
• Publication Date: 2019-07-16
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c9cp03052b
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Playing with the structural features of various hybrid materials enables to adjust physical properties of phenoxyl radicals. Abstract : The development of new open shell systems is essential for advances in spin science. In this work, we report the synthesis and characterization of three nanostructured materials, namely SBA-15 silicas, periodic mesoporous organosilicas (PMOs) and lamellar polysilsesquioxanes, all functionalized with the same diazene-based phenoxyl radical precursor. The impact of the nature of the material, i.e. loading of radical precursor and structure, on half-lifetimes ( t 1/2 ) and relaxation times of phenoxyl radicals was investigated. Although phenoxyl radicals are transient in solution, their t 1/2 range from hours to years at room temperature (RT) when they are embedded in nanostructured materials. The above mentioned functionalized materials were used to generate the corresponding phenoxyl radicals and their relaxation times were measured (〈 T 1e 〉 and T m ) from 50 K to RT. The results were rationalized in terms of limited mobility of the radical as a result of supramolecular interactions and structure rigidity. All these data show that it is possible to design functionalized nanostructured material with radicals possessing specific electronic relaxation properties which can be of interest in fields like DNP, organic magnetism or spin qubit.