Investigation of precipitation kinetics of FeCO3 by EQCM. (15th August 2018)

• Record Type: Journal Article
• Authors: Ma, Zheng; Yang, Yang; Brown, Bruce; Nesic, Srdjan; Singer, Marc
• Is Part Of: Corrosion science. Volume 141(2018)
• Page Start: 195
• Page End: 202
• Publication Date: 2018-08-15
• Subjects: EQCM -- Carbon dioxide corrosion -- Iron carbonate precipitation kinetics; Corrosion and anti-corrosives -- Periodicals; 620.11223
• DOI: 10.1016/j.corsci.2018.06.017
• Languages: English
• ISSNs: 0010-938X

Abstract

Highlights: An in-situ measurement technique, Electrochemical Quartz Crystal Microbalance (EQCM), was used to investigate FeCO3 precipitation kinetics. Repeatable and consistent precipitation rates were obtained across different substrates in the temperature range 50–80 °C by using EQCM. New values for the activation energy and kinetic constant for the FeCO3 precipitation were extracted. Abstract: Iron carbonate (FeCO3 ) is the most common corrosion product in aqueous CO2 corrosion of mild steel. When it forms, the FeCO3 corrosion product layer may be protective, by serving as a diffusion barrier and by affecting the rate of electrochemical reactions at the surface. In the present study, an Electrochemical Quartz Crystal Microbalance (EQCM) was used to investigate the kinetics of precipitation of FeCO3 from an aqueous CO2 corrosion environment. EQCM is a technique providing very accurate in-situ measurement of surface mass change, enabling also simultaneous electrochemical measurements. Three different substrates were used to conduct the FeCO3 precipitation experiments: a cathodically polarized gold-coated quartz crystal, a freely corroding iron-coated quartz crystal and a cathodically polarized iron-coated quartz crystal, at varied temperatures (50–80 °C). Precipitation rates of FeCO3 obtained by using EQCM were repeatable and consistent across different substrates. The obtained precipitation rates were used to determine the theoretical kinetic constant and the activation energy, which was then compared with those reported in the Sun and Nesic model (2008). Discrepancies between the predicted and experimental values were noticed at lower saturation levels and improvements in the model are proposed.