Spectroscopic Studies of Methimazole Reactivity toward the Aquapentacyanoferrate (II) Ion in Aqueous Solutions. Issue 5 (11th July 2012)
- Record Type:
- Journal Article
- Title:
- Spectroscopic Studies of Methimazole Reactivity toward the Aquapentacyanoferrate (II) Ion in Aqueous Solutions. Issue 5 (11th July 2012)
- Main Title:
- Spectroscopic Studies of Methimazole Reactivity toward the Aquapentacyanoferrate (II) Ion in Aqueous Solutions
- Authors:
- Cvijanović Cvijanović, D. D.
Damjanović Damjanović, V. V.
Picek Picek, I. I.
Foretić Foretić, B. B. - Abstract:
- Abstract : Methimazole (2-mercapto-1-methylimidazole, MMI) and its pentacyanoferrate (II) complex have been characterized by means of UV/Vis, Raman, and NMR spectroscopy. The reaction of MMI with aquapentacyanoferrate (II), [Fe(CN)5 (H2 O)] 3−, in buffered aqueous solutions yielded the [Fe(CN)5 (MMI)] 3− complex. It was found that only thione tautomer of MMI coordinates to the iron (II). The exceptionally stabile and inert complex was produced.
- Is Part Of:
- Spectroscopy. Volume 27:Issue 5/6(2012)
- Journal:
- Spectroscopy
- Issue:
- Volume 27:Issue 5/6(2012)
- Issue Display:
- Volume 27, Issue 5/6 (2012)
- Year:
- 2012
- Volume:
- 27
- Issue:
- 5/6
- Issue Sort Value:
- 2012-0027-NaN-0000
- Page Start:
- 509
- Page End:
- 514
- Publication Date:
- 2012-07-11
- Subjects:
- 2-mercapto-1-methylimidazole -- pentacyanoferrate (II) complexes -- spectroscopy
- DOI:
- 10.1155/2012/136058 ↗
- Languages:
- English
- ISSNs:
- 0712-4813
- Deposit Type:
- Legaldeposit
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- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library HMNTS - ELD Digital store
- Ingest File:
- 11128.xml