A Three‐Dimensional Tetraphenylíethene‐Based Metal–Organic Framework for Selective Gas Separation and Luminescence Sensing of Metal Ions. Issue 27 (18th May 2016)

• Record Type: Journal Article
• Authors: Yang, Wei; Chang, Ganggang; Wang, Hailong; Hu, Tong‐Liang; Yao, Zizhu; Alfooty, Khalid; Xiang, Shengchang; Chen, Banglin
• Other Names: Dietzel Pascal D. C. guestEditor.; Kitagawa Hiroshi guestEditor.
• Is Part Of: European journal of inorganic chemistry. Issue 27(2016)
• Page Start: 4470
• Page End: 4475
• Publication Date: 2016-05-18
• Subjects: Metal–organic frameworks -- Microporous materials -- Gas separation -- Luminescence -- Sensors -- Ligand design; Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.201600201
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract : A three‐dimensional porous metal–organic framework (MOF), UTSA‐86, made up of cadmium ions and a chromophoric tetraphenylethene‐based tetracarboxylate ligand, 4′, 4′′′, 4′′′′′, 4′′′′′′′‐(ethene‐1, 1, 2, 2‐tetrayl)tetrakis(1, 1′‐biphenyl‐4‐carboxylic acid (H4 ettc), has been synthesized and characterized by single‐crystal X‐ray diffraction analysis. This multifunctional MOF exhibits permanent porosity, selective gas uptake, and luminescence sensing of metal ions. Abstract : A three‐dimensional multifunctional metal–organic framework (MOF), UTSA‐86, made up of cadmium ions and a tetraphenylethene‐based tetracarboxylate ligand has been synthesized and characterized by single‐crystal X‐ray diffraction analysis. This MOF exhibits permanent porosity, selective gas uptake, and luminescence sensing of metal ions.