Ionic Hamiltonians for transition metal atoms: effective exchange coupling and Kondo temperature. (12th December 2016)

• Record Type: Journal Article
• Authors: Flores, F; Goldberg, E C
• Is Part Of: Journal of physics. Volume 29:Number 5(2017)
• Publication Date: 2016-12-12
• Subjects: ionic Hamiltonian -- Kondo -- spin fluctations -- inelastic electron scattering; Condensed matter -- Periodicals; Matière condensée -- Périodiques; Vaste stoffen; Vloeistoffen; Natuurkunde; Electronic journals; Computer network resources; 530.4105
• DOI: 10.1088/1361-648X/aa4dda
• Languages: English
• ISSNs: 0953-8984

Abstract

Abstract: An ionic Hamiltonian for describing the interaction between a metal and a d -shell transition metal atom having an orbital singlet state is introduced and its properties analyzed using the Schrieffer–Wolf transformation (exchange coupling) and the poor man's scaling method (Kondo temperature). We find that the effective exchange coupling between the metal and the atom has an antiferromagnetic or a ferromagnetic interaction depending on the kind of atomic fluctuations, either S → S − 1 / 2 or S → S + 1 / 2, associated with the metal-atom coupling. We present a general scheme for all those processes and calculate, for the antiferromagnetic interaction, the corresponding Kondo-temperature.