Room temperature magnetism and metal to semiconducting transition in dilute Fe doped Sb1−xSex semiconducting alloy thin films. (3rd February 2015)

• Record Type: Journal Article
• Authors: Agrawal, Naveen; Sarkar, Mitesh; Chawda, Mukesh; Ganesan, V; Bodas, Dhananjay
• Is Part Of: Materials research express. Volume 2:Number 2(2015)
• Publication Date: 2015-02-03
• Subjects: thin films -- semiconductors -- magnetic properties -- electrical properties -- alloys -- atomic force microscopy; Materials science -- Research -- Periodicals; Materials science -- Periodicals; 620.11
• DOI: 10.1088/2053-1591/2/2/025902
• Languages: English
• ISSNs: 2053-1591

Abstract

Abstract: The magnetism was observed in very dilute Fe doped alloy thin film Fe0.008 Sb1− x Se x, for x = 0.01 to 0.10. These thin films were grown on silicon substrate using thermal evaporation technique. Structural, electrical, optical, charge carrier concentration measurement, surface morphology and magnetic properties were observed using glancing incidence x-ray diffraction (GIXRD), four probe resistivity, photoluminescence, Hall measurement, atomic force microscopy (AFM) and magnetic force microscopy (MFM) techniques, respectively. No peaks of iron were seen in GIXRD. The resistivity results show that activation energy increases with increase in selenium (Se) concentration. The Arrhenius plot reveals metallic behavior below room temperature. The low temperature conduction is explained by variable range-hopping mechanism, which fits very well in the temperature range 150–300 K. The decrease in density of states has been observed with increasing selenium concentration ( x = 0.01 to 0.10). There is a metal-to-semiconductor phase transition observed above room temperature. This transition temperature is Se concentration dependent. The particle size distribution ∼47–61 nm is evaluated using AFM images. These thin films exhibit ferromagnetic interactions at room temperature.