Synthesis and growth mechanism of carbon nanotubes growing on carbon fiber surfaces with improved tensile strength. (19th July 2018)

• Record Type: Journal Article
• Authors: Qin, Jianjie; Wang, Chengguo; Wang, Yanxiang; Lu, Ruijiao; Zheng, Linbao; Wang, Xinghui; Yao, Zhiqiang; Gao, Quan; Wei, Huazhen
• Is Part Of: Nanotechnology. Volume 29:Number 39(2018)
• Publication Date: 2018-07-19
• Subjects: CNTs -- tensile strength -- CVD -- growth mechanism; Nanotechnology -- Periodicals; Nanotechnology -- Periodicals; Nanotechnology; Publications périodiques; Nanotechnologies; Periodicals; 620.5
• DOI: 10.1088/1361-6528/aad10c
• Languages: English
• ISSNs: 0957-4484

Abstract

Abstract: An effective approach has been developed for the catalytic decomposition of acetylene (C2 H2 ) by chemical vapor deposition (CVD), to achieve homogeneous growth of carbon nanotubes (CNTs) on the surfaces of carbon fibers. The morphology of CNTs grown on carbon fiber surfaces was observed by a scanning electron microscope and high-resolution transmission electron microscope, which revealed the uniform coverage of CNTs on the carbon fiber surfaces. The single fiber tensile test demonstrated that the tensile strength of carbon fibers could be increased by more than 12% with the catalytic growth of CNTs on their surface. The reparation of the damage caused during the formation of catalyst nanoparticles, and the cross-link of neighboring graphite crystallites induced by CNTs all occurred during the CVD process, which were considered to be the main reasons for improvement. The growth mechanism model of CNTs formation was established based on the thermodynamics principle and the interface microstructure of CNT-grown carbon fiber, illuminating the detailed mechanism for the growth of CNTs and the change of the shape of catalyst particles.