Hierarchical multi-layered molybdenum carbide encapsulated oxidized carbon nanofiber for selective electrochemical detection of antimicrobial agents: inter-connected path in multi-layered structure for efficient electron transfer. Issue 7 (21st May 2019)

• Record Type: Journal Article
• Authors: Ramki, Settu; Sukanya, Ramaraj; Chen, Shen-Ming; Sakthivel, Mani
• Is Part Of: Inorganic chemistry frontiers. Volume 6:Issue 7(2019)
• Page Start: 1680
• Page End: 1693
• Publication Date: 2019-05-21
• Subjects: Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9qi00158a
• Languages: English
• ISSNs: 2052-1553

Abstract

Abstract : The schematic illustration for electrochemical sensing of MTZ at Mo2 /C/f-CNF modified GCE. Abstract : Metal carbides are an emerging class of electrode materials for various electrochemical applications. Herein, we have synthesized the molybdenum carbide (Mo2 C) hexagons via a template assisted method. Subsequently, the Mo2 C hexagons were integrated with functionalized carbon nanofiber (f-CNF) via the ultra-sonication method. The prepared Mo2 C and Mo2 C/f-CNF composites were analyzed using different techniques such as XRD, RAMAN, HR-TEM, and ESCA. The HR-TEM images of Mo2 /C/f-CNF composite evidently proved that the Mo2 /C hexagons are well integrated on surface of f-CNF along with a connection part for efficient electron transfer from Mo2 C to f-CNF structure. Due to its excellent electrochemical properties, the proposed Mo2 C/f-CNF nanocomposite modified GCE was developed as an efficient electrode for the electrochemical detection of metronidazole (MTZ). As expected, Mo2 C/f-CNF/GCE achieved the ultra-low detection limit of 0.002 μM and the linear range of 0.04–647.7 μM in sensing of MTZ. Mo2 C/f-CNF/GCE was successfully for real time detection in human urine samples. All the electrochemical results clearly proved that the Mo2 C/f-CNF composite is an effective electrode for detection of MTZ.