Synthesis, crystal structure and Hirshfeld surface analysis of a new 0D nanostructured [{Ar-Cl)tetra-azo-S}2Hg] coordination supramolecular compound derived from phenyl isothiocyanate ligand. Issue 10 (19th May 2019)

• Record Type: Journal Article
• Authors: Mohammadi, Mohammad Kazem; Khoshnavazi, Roushan; Geravand, Samira; Karimi, Mehdi; Retailleau, Pascal; Masoudiasl, Ardavan; Hayati, Payam; Mahmoudi, Ghodrat
• Is Part Of: Journal of coordination chemistry. Volume 72:Issue 10(2019)
• Page Start: 1671
• Page End: 1682
• Publication Date: 2019-05-19
• Subjects: Nanoparticles -- coordination supramolecular compound -- Hirshfeld surface analysis -- ultrasonic -- morphology; Coordination compounds -- Periodicals; 541.2242
• DOI: 10.1080/00958972.2019.1613531
• Languages: English
• ISSNs: 0095-8972

Abstract

Abstract: Nanoparticles of a new mercury(II) coordination supramolecular compound (CSC), [{(Ar-Cl)tetra-azo-S}2 Hg] (1 ), were synthesized using a sonochemical process and characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and elemental analyses (EA). The single crystal X-ray data of1 revealed that the Hg ion was two-coordinate. Also, Hirshfeld surface analysis of1 showed the effective role of interactions related to nitrogen atoms in stabilization of the supramolecular structure. The role of ultrasonic power, sonicating time and temperature on the size and morphology of the nano-structured compound obtained from1 were investigated. The results indicated that increasing temperature and sonication power and decreasing sonication time led to reducing the particle size. Graphical Abstract: