Mixed Stacked Charge‐Transfer π‐Organic Materials Based on Anthracenyl Boronic Acid. Issue 47 (21st December 2017)

• Record Type: Journal Article
• Authors: Petroselli, Manuel; Mosca, Sara; Martí‐Rujas, Javier; Comelli, Daniela; Cametti, Massimo
• Is Part Of: European journal of organic chemistry. Issue 47(2017)
• Page Start: 7190
• Page End: 7194
• Publication Date: 2017-12-21
• Subjects: Functional organic materials -- Charge‐transfer -- Boronic acids -- Solid‐state Fluorescence -- Self‐assembly -- Hydrogen bonds; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.201701555
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract : Anthracenyl boronic acid derivatives are used for the first time as hydrogen‐bond and π‐donors to obtain a series of novel 1:1 mixed stacked π‐organic materials with interesting structural, UV/Vis reflectance and emission properties by reaction with quinones in both solution and the solid. The underlying principles, which have led to hetero‐assembly, could be applied to construct a potentially large variety of mixed stacked π‐organic solid‐state materials for technological applications. Abstract : The hetero‐assembly principles to synthesize novel charge‐transfer materials by reacting HB‐ and π‐donor anthracenyl boronic acids with quinones, both in solution and the solid state, are described.