Intramolecular nitration–aminocarbonylation of unactivated olefins: metal-free synthesis of γ-lactams. Issue 54 (19th June 2019)
- Record Type:
- Journal Article
- Title:
- Intramolecular nitration–aminocarbonylation of unactivated olefins: metal-free synthesis of γ-lactams. Issue 54 (19th June 2019)
- Main Title:
- Intramolecular nitration–aminocarbonylation of unactivated olefins: metal-free synthesis of γ-lactams
- Authors:
- Chen, Dong
Ji, Meishan
Zhu, Chen - Abstract:
- Abstract : A novel, metal-free synthesis of valuable γ-lactams through the radical-mediated nitration–aminocarbonylation of unactivated olefins is reported. Abstract : Disclosed herein is a novel, metal-free synthesis of γ-lactams through the radical-mediated nitration–aminocarbonylation of unactivated olefins. The reaction is initiated by a nitro radical generated from the homolysis of tert -butyl nitrite. The intramolecular cyanamide serves as the aminocarbonylating reagent. This protocol offers an environment-benign method to produce the synthetically valuable nitromethyl substituted γ-lactams.
- Is Part Of:
- Chemical communications. Volume 55:Issue 54(2019)
- Journal:
- Chemical communications
- Issue:
- Volume 55:Issue 54(2019)
- Issue Display:
- Volume 55, Issue 54 (2019)
- Year:
- 2019
- Volume:
- 55
- Issue:
- 54
- Issue Sort Value:
- 2019-0055-0054-0000
- Page Start:
- 7796
- Page End:
- 7799
- Publication Date:
- 2019-06-19
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9cc03736e ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 10972.xml