2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant. Issue 54 (18th June 2019)

• Record Type: Journal Article
• Authors: Yusubov, Mekhman S.; Soldatova, Natalia S.; Postnikov, Pavel S.; Valiev, Rashid R.; Yoshimura, Akira; Wirth, Thomas; Nemykin, Victor N.; Zhdankin, Viktor V.
• Is Part Of: Chemical communications. Volume 55:Issue 54(2019)
• Page Start: 7760
• Page End: 7763
• Publication Date: 2019-06-18
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c9cc04203b
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A new powerful hypervalent iodine(v ) oxidant, a ditriflate derivative of 2-iodoxybenzoic acid (IBX), was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. Abstract : A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.