H2O-controlled selective thiocyanation and alkenylation of ketene dithioacetals under electrochemical oxidation. Issue 13 (3rd June 2019)

• Record Type: Journal Article
• Authors: Wen, Jiangwei; Zhang, Longfei; Yang, Xiaoting; Niu, Cong; Wang, Shuangfeng; Wei, Wei; Sun, Xuejun; Yang, Jianjing; Wang, Hua
• Is Part Of: Green chemistry. Volume 21:Issue 13(2019)
• Page Start: 3597
• Page End: 3601
• Publication Date: 2019-06-03
• Subjects: Environmental chemistry -- Industrial applications -- Periodicals; Environmental management -- Periodicals; 660
• DOI: 10.1039/c9gc01351b
• Languages: English
• ISSNs: 1463-9262

Abstract

Abstract : Efficient and H2 O-controlled selective thiocyanation and alkenylation of internal olefins, to afford tetrasubstituted olefins under electrochemical oxidation, has been successfully developed. Abstract : Efficient and H2 O-controlled selective thiocyanation and alkenylation of internal olefins, to afford tetrasubstituted olefins under electrochemical oxidation, has been successfully developed. This transformation can present a critical feature wherein neither exogenous oxidants nor catalysts are required. Notably, such an electrochemical oxidation-based synthetic strategy exhibits excellent tolerance towards functional groups and can be easily scaled up with good efficiency.