Classification of ANFO samples based on their fuel composition by GC–MS and FTIR combined with chemometrics. (August 2019)

• Record Type: Journal Article
• Authors: Suppajariyawat, Praew; Elie, Mathieu; Baron, Mark; Gonzalez-Rodriguez, Jose
• Is Part Of: Forensic science international. Volume 301(2019)
• Page Start: 415
• Page End: 425
• Publication Date: 2019-08
• Subjects: ANFO explosives -- Diesel -- FAMEs -- GCMS -- FTIR -- Chemometrics; Medical jurisprudence -- Periodicals; Chemistry, Forensic -- Periodicals; Forensic Medicine -- Periodicals; Médecine légale -- Périodiques; Chimie légale -- Périodiques; Gerechtelijke geneeskunde; Gerechtelijke chemie; Gerechtelijke psychiatrie; Chemistry, Forensic; Medical jurisprudence; Electronic journals; Periodicals; Electronic journals; 614.1
• DOI: 10.1016/j.forsciint.2019.06.001
• Languages: English
• ISSNs: 0379-0738

Abstract

Highlights: Diesel was successfully extracted from ANFO samples and able to be analysed by GC–MS. Four fatty acid methyl esters (FAMEs) were observed in some diesel extracts from ANFO samples by GC–MS. GC–MS and FTIR combined with PCA were successfully used to classify ANFO samples with high degree of accuracy. Abstract: Ammonium nitrate fuel oil (ANFO) is one of the most favorite explosives used in terrorist attacks. This explosive is a complex mixture of 95–96% ammonium nitrate (AN) and 4–5% liquid hydrocarbons (fuel oil). In this study, we analyze a variety of ANFO explosive mixtures in order to classify their different sources of origin by observing the difference in fuel components. The study was performed by mixing ammonium nitrate with eight different diesel brands collected in Lincoln, UK in two seasons (winter and summer). The samples were extracted using appropriate solvent and extracts were subsequently analyzed in sextuplicate by gas chromatography―mass spectrometry (GC–MS) and Fourier transform infrared spectroscopy (FTIR). A classification model was performed using principal component analysis (PCA) and Lineal Discriminant Analysis (LDA). In this study, four fatty acid methyl ester (FAME) contents were observed by GC–MS in all summer samples but found lack in some winter sample resulting in seasonal variation effect. The classification of pre-blast ANFO samples was achieved using GC–MS and FTIR in a combination with PCA/LDA. The results significantly showed the variation of specific diesel components and providing different classification performance among ANFO samples with high classification performance. Therefore, this study can be beneficial in forensic investigation that the use of diesel components are able to classify among different ANFO samples.