A Catalytic Microwave Process for Superfast Preparation of High‐Quality Reduced Graphene Oxide. Issue 49 (4th October 2017)

• Record Type: Journal Article
• Authors: Liu, Runze; Zhang, Yu; Ning, Zhenjian; Xu, Yuxi
• Is Part Of: Angewandte Chemie international edition. Volume 56:Issue 49(2017)
• Page Start: 15677
• Page End: 15682
• Publication Date: 2017-10-04
• Subjects: anode materials -- graphene -- lithium-ion batteries -- microwave chemistry -- sodium-ion batteries; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201708714
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Herein we report that a small amount of graphite can unexpectedly act as the catalyst to greatly promote the microwave exfoliation and reduction of graphite oxide in ambient air. The reaction can be finished in a few seconds in contrast to more than ten minutes without catalyst. The catalytic microwave exfoliated graphite oxide (CMEGO) is of higher quality than the traditional microwave exfoliated graphite oxide, including a much higher exfoliation degree with thinner graphene sheets and higher specific surface area (886 m 2 g −1 vs. 466 m 2 g −1 ), a much larger C/O ratio (19.4 vs. 6.3) and a higher lattice crystallinity, as well as significantly improved electrical conductivity (53180 S m −1 vs. 5140 S m −1 ). The CMEGO is used as anode for lithium‐ion battery (LIB) and sodium‐ion battery (SIB), and delivers ultrahigh reversible capacities, remarkable rate capabilities, and superior cycling stabilities in both LIB and SIB. Abstract : Reduced to clear : A small amount of graphite unexpectedly acts as the catalyst to greatly promote the microwave exfoliation and reduction of graphite oxide (GO) in ambient air. The catalytic microwave exfoliated graphite oxide (CMEGO) product has ultrahigh electrochemical performances as anodes for both lithium‐ion and sodium‐ion batteries.