The surface engineering of cobalt carbide spheres through N, B co-doping achieved by room-temperature in situ anchoring effects for active and durable multifunctional electrocatalysts. Issue 24 (6th June 2019)

• Record Type: Journal Article
• Authors: Ma, Xinzhi; Li, Kaiyue; Zhang, Xiao; Wei, Bo; Yang, Huan; Liu, Lina; Zhang, Mingyi; Zhang, Xitian; Chen, Yujin
• Is Part Of: Journal of materials chemistry. Volume 7:Issue 24(2019)
• Page Start: 14904
• Page End: 14915
• Publication Date: 2019-06-06
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c9ta03762d
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : B doping and surface engineering of a N-containing Co3 C alloy at room temperature are simultaneously achieved, endowing the resultant catalyst with excellent and stable multifunctional activities. Abstract : Zinc–air batteries and full water-splitting devices, as environmentally friendly electrochemical energy storage and conversion systems, have drawn extensive attention. However, effective, low-cost and durable electrochemical catalysts for the involved oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) are highly desired. Herein, a new N, B co-doped Co3 C multifunctional catalyst with enhanced ORR, OER and HER activities, as well as improved ORR and OER stabilities, in alkaline media has been synthesized. The strategy used, immersing N-doped Co3 C in NaBH4 solution, not only achieves N, B co-doping via the N anchoring effect to B at room temperature for the first time, but also engineers the outmost surface of Co3 C-N by forming nanosheet arrays. Besides, Co–N x –B and N–B bonds have been successful produced via the anchoring effect of N during the immersion treatment, which is proved by the X-ray photoelectron spectroscopy (XPS) results. In particular, both liquid and solid-state Zn–air batteries that are equipped with Co3 C-NB as air-cathodes all exhibit superior cycling stabilities over those with Co3 C, N-doped Co3 C and Pt/C + IrO2 air-cathodes. Furthermore, a Co3 C-NB-based full water splitting device can be successfully driven using two solid-state zinc–air batteries with a Co3 C-NB air-cathode in series.