EGOFET Gated by a Molecular Electronic Switch: A Single‐Device Memory Cell. (18th March 2019) - Parkula, Vitaliy
Abstract: Electrolyte‐gated organic field‐effect transistors (EGOFETs) exploit the transduction of interfacial phenomena, such as biorecognition or redox processes, into detectable changes of electrical response. Here, it is shown that, beyond sensing applications, EGOFETs may act effectively as memory devices, through the functionalization of the gate electrode with a self‐assembly monolayer comprising a switching molecule undergoing a large and persistent change of dipole moment, upon application of a small (0.6 V) programming potential. This first example of a switchable EGOFET device with memory retention is based on a tetrathiafulvalene derivative self‐assembled on gold and an aqueous buffer as electrolyte in a microfluidic assembly. Changes of the self‐assembled monolayer redox state lead to variations of the gate electrochemical potential and, as a consequence, the EGOFET's threshold voltage undergoes reversible shifts larger than 100 mV. The distinctive electrical readout upon different redox states opens the possibility of writing and erasing information, thus making the transistor behave as a single memory cell. Abstract : The first demonstration of the memory effect in a liquid‐gated organic electronic device is presented. A new type of electrolyte‐gated organic field‐effect transistor (EGOFET) with double top planar gates switched by an electroactive molecule is described. This EGOFET with memory retention is based on a tetrathiafulvalene derivative self‐assembled on gold and an aqueous buffer as electrolyte in a microfluidic assembly.