Allylation of aldehydes by dual photoredox and nickel catalysis. Issue 48 (16th May 2019)

• Record Type: Journal Article
• Authors: Gualandi, Andrea; Rodeghiero, Giacomo; Faraone, Adriana; Patuzzo, Filippo; Marchini, Marianna; Calogero, Francesco; Perciaccante, Rossana; Jansen, Thomas Paul; Ceroni, Paola; Cozzi, Pier Giorgio
• Is Part Of: Chemical communications. Volume 55:Issue 48(2019)
• Page Start: 6838
• Page End: 6841
• Publication Date: 2019-05-16
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c9cc03344k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. Abstract : Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. The process utilizes the combination of a Ni(ii ) complex, [Ru(bpy)3 ] 2+ as a photoredox catalyst, and allylacetate under blue LED irradiation, and allows the synthesis of a large variety of homoallylic alcohols.