Mechanocaloric effects in superionic thin films from atomistic simulations. Issue 1 (December 2017)

• Record Type: Journal Article
• Authors: Sagotra, Arun; Errandonea, Daniel; Cazorla, Claudio
• Is Part Of: Nature communications. Volume 8:Issue 1(2017)
• Page Start: 1
• Page End: 7
• Publication Date: 2017-12
• Subjects: Biology -- Periodicals; Physical sciences -- Periodicals; 505
• DOI: 10.1038/s41467-017-01081-7
• Languages: English
• ISSNs: 2041-1723

Abstract

Abstract Solid-state cooling is an energy-efficient and scalable refrigeration technology that exploits the adiabatic variation of a crystalline order parameter under an external field (electric, magnetic, or mechanic). The mechanocaloric effect bears one of the greatest cooling potentials in terms of energy efficiency owing to its large available latent heat. Here we show that giant mechanocaloric effects occur in thin films of well-known families of fast-ion conductors, namely Li-rich (Li3 OCl) and type-I (AgI), an abundant class of materials that routinely are employed in electrochemistry cells. Our simulations reveal that at room temperature AgI undergoes an adiabatic temperature shift of 38 K under a biaxial stress of 1 GPa. Likewise, Li3 OCl displays a cooling capacity of 9 K under similar mechanical conditions although at a considerably higher temperature. We also show that ionic vacancies have a detrimental effect on the cooling performance of superionic thin films. Our findings should motivate experimental mechanocaloric searches in a wide variety of already known superionic materials. Mechanocaloric effects are a promising path towards solid-state cooling. Here the authors perform atomistic simulations on the well-known fast-ion conductor silver iodide and computationally predict a sizeable mechanocaloric effect under biaxial strain.