Critical evaluation of experimental data of solution enthalpy of zirconium in liquid aluminum. (January 2019)

• Record Type: Journal Article
• Authors: Barrachin, M.; Gajavalli, K.; Decreton, A.; Virot, F.; Bénigni, P.; Rogez, J.; Mikaelian, G.; Fischer, E.; Lomello-Tafin, M.; Antion, C.; Janghorban, A.
• Is Part Of: Journal of chemical thermodynamics. Volume 128(2019)
• Page Start: 295
• Page End: 304
• Publication Date: 2019-01
• Subjects: Thermodynamics -- Periodicals; Thermochemistry -- Periodicals; Thermodynamique -- Périodiques; Thermochimie -- Périodiques; Thermochemistry; Thermodynamics; Periodicals; 541.369
• DOI: 10.1016/j.jct.2018.08.010
• Languages: English
• ISSNs: 0021-9614

Abstract

Highlights: The Zr dissolution in liquid Al in past calorimetry experiments are re-interpreted. They must be considered in terms of transformation of Zr into Al3 Zr. It puts in question past standard enthalpy measurements of compounds in some systems. Abstract: The aim of the present paper is to propose a new interpretation of the zirconium dissolution in liquid aluminum calorimetry experiments performed in the past in order to reconcile some apparently contradictory results and observations. It is supported by the development of a dissolution kinetics model. We show that probably most of the experiments interpreted in terms of dissolution must be considered in terms of (partial or total) transformation of zirconium into zirconium aluminide (Al3 Zr). In addition, on the basis of the developed model, we propose some recommendations in terms of experimental conditions to improve the dissolution process. These recommendations are consistent with some empirical rules derived in the past. It also puts in question past standard enthalpy measurements of some compounds in the Cu-Zr, Ni-Zr, Co-Zr and U-Zr systems.