Rayleigh–Brillouin light scattering spectroscopy of nitrous oxide (N2O). (February 2018)

• Record Type: Journal Article
• Authors: Wang, Y.; Liang, K.; van de Water, W.; Marques, W.; Ubachs, W.
• Is Part Of: Journal of quantitative spectroscopy & radiative transfer. Volume 206(2018)
• Page Start: 63
• Page End: 69
• Publication Date: 2018-02
• Subjects: Rayleigh–Brillouin scattering -- N2O -- Tenti-model; Spectrum analysis -- Periodicals; Radiation -- Periodicals; Analyse spectrale -- Périodiques; Rayonnement -- Périodiques; Radiation; Spectrum analysis; Periodicals; 543.0858
• DOI: 10.1016/j.jqsrt.2017.10.029
• Languages: English
• ISSNs: 0022-4073

Abstract

Highlights: High signal-to-noise Rayleigh–Brillouin scattering data in N2 O gas. Good agreement with Tenti model in kinetic regime. Good agreement with hydrodynamic model at high pressures. Determination of bulk viscosity for N2 O gas. Abstract: High signal-to-noise and high-resolution light scattering spectra are measured for nitrous oxide (N2 O) gas at an incident wavelength of 403.00 nm, at 90° scattering, at room temperature and at gas pressures in the range 0.5 − 4 bar. The resulting Rayleigh–Brillouin light scattering spectra are compared to a number of models describing in an approximate manner the collisional dynamics and energy transfer in this gaseous medium of this polyatomic molecular species. The Tenti-S6 model, based on macroscopic gas transport coefficients, reproduces the scattering profiles in the entire pressure range at less than 2% deviation at a similar level as does the alternative kinetic Grad's 6-moment model, which is based on the internal collisional relaxation as a decisive parameter. A hydrodynamic model fails to reproduce experimental spectra for the low pressures of 0.5-1 bar, but yields very good agreement ( < 1%) in the pressure range 2 − 4 bar. While these three models have a different physical basis the internal molecular relaxation derived can for all three be described in terms of a bulk viscosity of η b ∼ ( 6 ± 2 ) × 10 − 5 Pa · s. A 'rough-sphere' model, previously shown to be effective to describe light scattering in SF6 gas, is not found to be suitable, likely in view of the non-sphericity and asymmetry of the N-N-O structured linear polyatomic molecule.